Technically the link cables only need to be 50% of the capacity of the main feed, ( because they'll be carrying 50% of the total current) . Your main feed looks like 10mm so anything over a paltry 5mm will suffice. What we go for will depend on how much future proofing you want to build in, we can discuss that.....along with quite a lot more.
Biggest issue is cable size between
solar controller and batteries, looks like you've currently got about 3m of 1.5mm flex. At full sun this cable will be dropping approx 1/2 a volt so when the controller thinks your
battery is full and reduces its charge current because it senses 14.6 volts the actual
battery will only be at 14.1v and way under charged, this (IMO) is why you seem to be able to recharge the leisure
battery very quickly and why you don't seem to have a lot of useable capacity.
We should consider moving the controller closer to the batteries and/or upping the cable gauge between SCC and batteries.
As I've expressed previously (way back in this thread) you should consider a mppt controller, either get a Votronic with a maintenance output to the starter
battery or a single output mppt and I'll make you up a 'little Gizmo' that'll fit between the leisure and starter
battery and keep the starter maintained, it's basically like the Ablemail, Stirling etc
battery maintainers but better and cheaper. I've got one fitted to my van and it works like a charm. (I'm going to post details of this device soon for anyone interested)
I think the best thing you and I can do is have a discussion about your usage (current and projected) and devise a plan and at that point ( if you feel a need to get qualification before proceeding) post details here so anyone with an opinion can chip in. We then alter/modify the plan if needed and then get the job done.