I'm an electrician by trade and i see alot of amateur jobs that haven't come to harm by sheer luck. There's quite alot that can go wrong with a
battery, even though 12v is not enough to drive current through skin, a
battery is quite capable of releasing in excess of 500 amps if shorted, enough to send a spanner or the base of a van seat red hot in a very short space of time, let alone a thin piece of cable. All cables should be protected against overload and short circuit by at least one method, ideally 2. (IE insulation AND fuses /max demand calc etc) I'd size a cable according to ohms law and power equations, looking at how much it may reasonably draw in either fault or operational conditions to avoid overheating/melting. A 12v 2400w
inverter can pull approx 200 (2400w/12v=200a)amps continuously so your looking at cables at least twice the thickness of those coming in your house to supply such equipment. So about 50mm2 between primary and supply, 35mm between 1st & 2nd
battery if a 3
battery setup, and 25mm between 2&3 or on a 2
battery setup if all batterys are equal size and type. Welding cable is often pure copper so better that than jump leads which are often mixed with aluminium and can carry far less current for size. I believe regulations state the need for protection against vibration work hardening and subsequent failure of cables in vehicles, another reason to pick fine strand flexible copper cable over house type cable or aluminium. I'd size a
fuse to not pop on max demand, and cables larger than that so they are protected. Personally, as well as sc/oc fuses in the positives as close as possible to the
battery terrminals and on every cable size change/final circuit, i also place a
fuse inline on the negative between the main and aux systems, that way if ever there's a bridge between chassis and aux live before the
fuse (say in an accident or when tightening the live with a metal spanner) it'll disconnect it. Serves as an isolator between the van primary system and expensive secondary system equipment if having welding done etc also.
As
battery cables are 2 way(charge and discharge) I'd also look at how much i want it to charge bearing in mind the the thinner the cable, the higher the resistance, the higher the volt drop between supply(alternator etc) and load/
battery, and the less the percentage of charge the
battery will finally obtain. A
battery will require the full 14.4 v to charge to 100%, so you are looking at obtaining as close to zero volt drop as possible in order to utilise the full capacity of the
battery and maximise its life. Volt drop calcs can be found online and is far more of an issue in 12v systems than 240v systems.
I'd also mention hydrogen build up, its released when charging and is highly explosive so make sure you vent large or powerful lead acid
battery systems.
Hope this helps, I'd agree with the majority of posters here, the more i learn about electricity the more I realise how dangerous it can be and how much of an art it can be to get the most out of a
battery system, so if in doubt consult an expert.