I've seen this in boats many times and my present boat has such a setup. In fact they make dual purpose batteries for this. But it wouldn't really be suitable for a motorhome.
But the way I read it is that the OP wants to add a second leisure battery in parallel l to the existing one. But I could be wrong.
That`s exactly how i read it as well Rob however it could have been worded better and it`s the last phrase really worries me
They simply want to add a second leisure battery but it will not be right next to the original so ..............................
1, What size cable do i need to use to connect the two leisure batteries together ?
2, Is the alterator capable of charging all three batteries, i.e. starter battery and two leisure batteries ?
Now the worrying bit
3, How to connect the two leisure batteries together ?
This is the worrying bit, they have got that completely wrong because to keep the voltage at 12 volt they need connecting in parallel and NOT in series.
To keep the system at 12 volts they need connecting in parallel, positive to positive and negative to negative which is correct for the OP`s motorhome
To make the system 24 volt they need connecting in series, positive to negative and negative to positive which is NOT correct for the OP`s motorhome
The OP does not have a clear idea on how to do it so it would be better and more importantly safer if someone else who is qualified does the job for them.
It`s pointless and achieves nothing just having a go at them.