The durite is a VSR, there is no fancy charging set up that I know of Colin, and had the van for four years.
Is this what you have?
View attachment 145109
It is an "Electrobloc" not Electric Block, also referred to just as ELBs
It is made by Schaudt (who is now owned by Lippert, an American company) , who in a way are the German version of Sargent - they make lots of different versions of the ELBs. In the same way as if you have a British motorhome, chances are you have a Sargent system, if you have a German Motorhome, you probably have an EBL system.
I fitted an Ablemail AMT12-2 maintainer to one of those EBL119s just a few days ago as it happens
For driving, the EBLs just have a relay split-charge setup, no B2B, and is activated by the D+ signal rather than a voltage like a VSR is.
As an aside, your info says "batteries are charged when
solar power is being used". Just for clarification, the EBLs (or at least most, including the one in the image) do not have a
solar regulator/controller in them. They have a connection where you can connect up the output of the
solar controller, but you need the controller - connecting up a panel to that connection would mean putting 20+V onto the
battery.
This is where my brain freezes David, no idea what exactly a B2B is, but I have one of these
https://amzn.eu/d/iKxw9fW to send charge to the LB from the VB when the engine is running, & Merlin's Gizmott to do the same in reverse when parked up to a lesser degree.
I'm not 100% convinced I actually need Lithium. Lead acid has been fine, but the idea of a drop in appeals, but as said, no pennies have been harmed yet.
Well, there is no such thing as a "drop in" Lithium unless you have a system that is ready to take Lithium. If you read the small print on these websites, there is usually a caveat to the "drop in" comment saying it is drop in when you have a van with compatible chargers.
Ref B2B, a
Battery-to-
Battery Charger is the same as a Smart Mains Charger, but instead of taking the power from 240V AC and converting it, it takes it from the Alternator and converts it to the voltage the
battery wants.
The difference between that and something like a VSR is the relay does no conversion, so you have no charge profile and optimization of charging the
battery. The key feature a B2B has that is important to the alternator and what sparked this thread is it limits the current to the rating of the B2B. IF you just connect the
battery to the alternator (which is what you are doing with a relay when on), the only limits are down to the resistance of the setup. With Lead Batteries, that tends to be its own limitation due to their internal resistance. With Lithium, the batteries have a very small resistance and so would try to suck up as much power as they can get, which could be more than the alternator can handle. Some people deal with that by using very long cables to add resistance, but a more sensible way (IMO anyway) is to use a B2B which does that for you as well as having other benefits.
(yes, I am simplifying the picture, before the links to Wikipedia articles start appearing

)
Personally, from what you are describing, I would suggest to stick with what you have, but replace your dying Leisure
Battery with a Lead Carbon
battery.