if you have the head off .then you must have had a blown head gasket ,as nobody takes the head of for a decoke nowadays for fun. .so the head will have been skimed and the valves removed ,they will have been reground and refitted and the had will be nice and clean .and the head preasure tested .all you need to do is make shure the mating surface of the engine block is clean of all the old gasket, you can clean of any carbon deposits on each piston with a wooden scraper dont use anything else as you may damage the piston tops or the bores . put it back together with a good quality gasket set. if your engine has a timing belt, not all do, then a new one is a must, dont reuse the old one. when all is replaced turn the engine over manualy a couple of times to make shure all is ok ie valve timing is set correctly, if the engine locks up then something is wrong, there is nothing worse than putting everything back trying to start the engine and finding the pistons and valves meet and destroy the engine (it has happend to the best of us ) check then check again is the way to go hopes this is of help