there are a few things here to consider and understand why the float voltage is 14.0V even though it is set at 13.8V ...
The most obvious one to check and probably quickest to dismiss is "Are there any another chargers that are active"? You could (unlikely, but only you will know) have another charger running and putting out 14V? The 14.0V that the MPPT is reporting is the voltage it is reading from the
battery. it does not necessarily mean that is the voltage the MPPT itself is putting out.
Assuming the above is not the case, you need to look at the setting of the MPPT controller. The
Victron Controller has an option to set Temperature compensation within the "
Battery" configuration
The default is -16.2mV per 1 Celcius over 'Standard'.
View attachment 119217
This is what it will look like in the settings page
View attachment 119216
What this means is for every 1 Celcius from 'Standard', the target outputs will vary from the configured values by 16.2mV - increased when temp is BELOW 'standard' and decreased when temp is ABOVE 'standard'.
The 'standard'
battery temp is 20C. If for example, the
battery temp is 8C (very possible at this time of year), the Float Voltage the Controller will aim to put out WILL actually be around 14.V, not 13.8V (will actually be 13.994V). So that 14.0V for float is perfectably possible.
Now there is another aspect to this as well .... You can see the temp the MPPT 'thinks' the
battery is at in the
Victron Connect. This is mine right now:
View attachment 119218
So if I have Temp Compensation enabled, my target voltages would be 0.11V higher than the values I set.
If you are using the
Victron MPPT in standalone mode, then the temperature reported is NOT the
battery temp, but the controller temp. Plus it is only updated at the time the controller wakes up first thing in the morning (this might have changed in some update, but I am not aware that it has). And first thing in the morning is usually pretty cold compared to the main part of the day.
What this means is you are compensating for a cold
battery, and not only that but compensating for the same temperature level throughout the day. I would maybe turn off the temp compensation in the settings UNLESS you have a
Victron SBS (Smart
Battery Sense), in which case the MPPT will get real time updates of the actual
battery temp and the compensation level will be accurate.
In YOUR case, you have the SBS so the temp compensation should be right.
HTH.