If you are asking is it ok to use the gas ( ie boiler) when driving then the answer is No. If you mean driving with the bottle valve open then I suppose it would be ok but if you're not using the gas then there's no need to have it turned on!
In the event of an accident, gas hose rupture is a real possibility but in the event of a fire then the simple fact is that the very presence of a gas bottle would be a big hazard for the emergency services, ruptured hose or not, in a fire the bottle is a potential bomb. Hence the LPG sticker on your gas cabinet door (thats assuming there is one present) !