The next time you have a trip in the van: ie loaded as normal with fuel, water etc., call in to a weighbridge and get them to weigh the van and both axles separately. This is the only sure way to know what your pressures should be.
This will first of all tell you if your van is overloaded (many are). It will give you the weight on each axle and the tyre companies can give you the recommended pressure for that particular loading. Although, in saying that, some tyre companies no longer do it.